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Preliminary Remarks (Ordinary black writing-ink)
Ordinary black writing-ink contains a mixture of the tannates and gallates of the proto and sesquioxide of iron. These are insoluble in water, and are suspended by means of gum. Creosote or essential oils are added to prevent moulding.
Many receipts are given for inks; those found below are reliable. As a general rule, the use of vinegar, logwood, and salts of copper is not to be recommended. Inks so prepared are richer at first, but will fade and act on pens.
Most ink is pale when first written with, but becomes dark; this is owing to oxidation. Such ink lasts better than that which is very black.
When ink fades, it is from a decomposition of the organic matter; it may be restored by brushing over with infusion of galls or solution of ferrocyanide of potassium. The durability of any ink is impaired by the use of steel pens.
Writing Fluids.
Ink which is blue when first used (Stark's, Stephens's, Arnold's) contains sulphate of indigo, or soluble Prussian blue. It is an ink which is a true solution, and not merely a suspended precipitate. The same is true of Runge's Chrome Ink. Marking Inks, Containing nitrate of silver, are not indelible; they may be removed by cyanide of potassium.
Carbon inks, such as coal-tar diluted with naphtha, are indelible. Aniline black is nearly indelible; it is turned yellowish, but not removed, by chlorine.
To make common Black Ink.
Pour 1 gall. of boiling soft water on 1 lb. of powdered galls, previously put into a proper vessel. Stop the mouth of the vessel, and set it in the sun in summer, or in winter where it may be warmed by any fire, and let it stand 2 or 3 days.
Then add lb. of green vitriol powdered, and, having stirred the mixture well together with a wooden spatula, let it stand again for 2 or 3 days, repeating the stirring, when add further to it 5 oz. of gum Arabic dissolved in a quart of boiling water; and, lastly, 2 oz. of alum; after which let the ink be strained through a coarse linen cloth for use.
Another. A good and durable black ink may be made by the following directions: To 2 pts. of water add 3 oz. of the dark-colored, rough-skinned Aleppo galls in gross powder, and of rasped logwood, green vitriol, and gum arabic, each, 1 oz. This mixture is to be put in a convenient vessel, and well shaken four or five times a day, for ten or twelve days, at the end of which time it will be fit for use, though it will improve by remaining longer on the ingredients.
Stark's Ink (Writing fluid).
Twelve oz. nut-galls, 8 oz. each, sulphate of indigo and copperas, a few cloves, 4 or 6 oz. of gum Arabie for a gallon of ink. The addition of the sulphate of indigo renders the ink more permanent